On join
From Scriptwiki
The on JOIN event trigger when a user joins a channel.
on <level>:JOIN:<#[,#]>:<commands>
Note that this event also triggers when you join a channel yourself.
Examples
on *:JOIN:#: { echo -t $chan < $+ $nick $+ > has just joined $chan $+ . }
This will echo whenever someone has joined a channel and echo it to this channel. You can use this to modify mIRC's layout.
on *:JOIN:#yourchan: { notice $nick Hello $nick $+ ! Enjoy your stay here in $chan $+ . }
This will notice everyone joining #yourchan (you have to replace it with your chan of course). You can use it to have your own welcome-message.
on me:*:JOIN:#: { echo -s I have just joined $chan }
The example reacts on you joining a channel. Note that it is no mistake, the prefix is "me:".
See Also
To react on parts, take a look at the On part event.